| Date | Home | Away | Result |
|---|---|---|---|
| 6/4/23 11:30 AM | Real Madrid | Athletic Bilbao | 1-1 |
| 6/4/23 11:30 AM | FC Villarreal | Atletico Madrid | 2-2 |
| 6/4/23 11:30 AM | CA Osasuna | FC Girona | 2-1 |
| 6/4/23 11:30 AM | RCD Mallorca | Rayo Vallecano | 3-0 |
| 6/4/23 11:30 AM | Real Sociedad | FC Sevilla | 2-1 |
| 6/4/23 2:00 PM | Real Betis Sevilla | FC Valencia | 1-1 |
| 6/4/23 2:00 PM | Celta Vigo | FC Barcelona | 2-1 |
| 6/4/23 2:00 PM | Real Valladolid | FC Getafe | 0-0 |
| 6/4/23 2:00 PM | FC Elche | FC Cadiz | 1-1 |
| 6/4/23 2:00 PM | Espanyol Barcelona | UD Almeria | 3-3 |