| Date | Home | Away | Result |
|---|---|---|---|
| 6/1/13 10:00 AM | Real Madrid | CA Osasuna | 4-2 |
| 6/1/13 12:00 PM | FC Barcelona | FC Malaga | 4-1 |
| 6/1/13 2:00 PM | UD Levante | Real Betis Sevilla | 1-1 |
| 6/1/13 2:00 PM | Deportivo La Coruna | Real Sociedad | 0-1 |
| 6/1/13 2:00 PM | Rayo Vallecano | Athletic Bilbao | 2-2 |
| 6/1/13 2:00 PM | RCD Mallorca | Real Valladolid | 4-2 |
| 6/1/13 2:00 PM | Celta Vigo | Espanyol Barcelona | 1-0 |
| 6/1/13 2:00 PM | Real Saragossa | Atletico Madrid | 1-3 |
| 6/1/13 2:00 PM | FC Granada | FC Getafe | 2-0 |
| 6/1/13 2:00 PM | FC Sevilla | FC Valencia | 4-3 |